Bookcover of Transition Metal Nanocluster Catalysts and Chemical Hydrogen Storage
Booktitle:

Transition Metal Nanocluster Catalysts and Chemical Hydrogen Storage

Nickel, Cobalt and Ruthenium Nanoclusters as Catalyst in Hydrogen Generation from Sodium Borohydride and Ammonia Borane

LAP LAMBERT Academic Publishing (2012-03-20 )

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ISBN-13:

978-3-8484-3799-3

ISBN-10:
3848437996
EAN:
9783848437993
Book language:
English
Blurb/Shorttext:
The storage of hydrogen is still a major hurdle in front of the hydrogen economy. One conceptual solution is the generation of hydrogen from chemical compounds having high gravimetric and volumetric hydrogen storage capacity such as boron-nitrogen compounds. Recently, sodium borohydride and ammonia borane are considered to be the most promising ones among all other chemical hydrogen storage materials owing to their remarkable gravimetric hydrogen contents and stability in the solid state. The hydrogen stored in NaBH4 and H3NBH3 can be release via hydrolysis route. However, a suitable catalyst is required to generate hydrogen from their hydrolysis at desired rate. An efficient way of increasing catalytic activity of a heterogeneous catalyst is the use of transition metal nanoclusters (NCs) which are more active catalysts than the respective bulk metal owing to their high surface-to-volume ratio. Via this research work, we present our detailed study on the synthesis and characterization of water soluble polymer stabilized nickel(0), cobalt(0) and ruthenium(0) NCs as catalyst in hydrogen generation from the hydrolysis of NaBH4 and H3NBH3.
Publishing house:
LAP LAMBERT Academic Publishing
Website:
http://www.lap-publishing.com/
By (author) :
Önder Metin
Number of pages:
180
Published on:
2012-03-20
Stock:
Available
Category:
Chemistry
Price:
5349.42 руб
Keywords:
Polymer, Nickel, Catalyst, Cobalt, ruthenium, Transition metal nanoclusters, Poly(N-viny-2-pyrrolidone), Poly(4-styrene sulfonicacid-co-maleic acid), Hydrolysis of sodium borohydride, Hydrolysis of ammonia borane, Chemical hydrogen storage

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